Synthesis,characterization and catalytic activities of mononuclear complexes;
单核配合物的合成、表征及多酚氧化酶活性研究
The binuclear complex [Cu 2(TS)(H 2O)]·H 2O, where TS donates the binuclearing ligand derived from the schiff base N,N'_bis(3_carboxylsalicylidene)trimethylenediamine, was obtained through the selfdecomposition of mononuclear complex Na 2CuTS·H 2O in the methanol/water.
利用单核配合物Na2 CuTS·H2 O在溶剂中的不稳定性质 ,自分解并重新组装得到了双核配合物 [Cu2 (TS)(H2 O) ]·H2 O 。
A synthetic method of LnH2salen complexes was described and a series of binuclear complexes were obtained.
合成了稀土N,N-亚乙基双(水杨醛缩亚胺)(H2salen)双核配合物,通过元素分析、热分析、紫外、红外、远红外光谱、磁化率及1H、13CNMR谱与T1的测定,确定了他们与前人合成的配合物有所不同,其化学组成为[Ln2(H2salen)3(NO3)4](NO3)2·3H2O(Ln=La,Pr,Nd,Sm,Gd,Tb,Er,Yb及Y),并对它们的配位作用、波谱及可能应用进行了探讨。
Six new binary complexes Cr(L-A)3[L=H, 2-OCH3, 4-OCH2CH3; A=2-(COO)C6H4CONHC6H4-,COOCH2CH2CONHC6H4-]and four new binuclear complexes Cr(L-A)3?/2CuX2[L=2-OCH3 , 4-OCH2CH3 : X=C1 , Br] were synthesized and characterized by elemental analysis, infrared and ultraviolet spectra as well as molar conductors.
本文报道了六种二元配合物Cr(L-A)_3[L=H,2-OCH_3,4-OCH_2CH_3;A=2-(COO)C_6H_4CONHC_6H_4-,COOCH_2CH_2CONHC_6H_4-]和四种双核配合物Cr(L-A)_3·3/2CuX_2[其中L=2-OCH_3,4-OCH_2CH_3;X=Cl,Br]的合成。
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