Catalyzed by FeCl3,the direct deoxygenative chlorination of carbonyl compounds(1) into their corresponding chlorides(2) has been achieved in the presence of dichloromethylsilane(MeSiHCl2).
在甲基二氯氢硅烷存在下,FeCl3催化羰基化合物(1)的还原氯代反应,合成了氯代烷烃(2)。
Cyclohexylmethyldichlorosilane(CMCS) was synthesized from dichloromethylsilane(DCMS) and cyclohexene via hydrosilylation with silica supported Pt catalyst.
在硅胶负载铂催化剂的催化作用下,以甲基二氯氢硅烷(DCMS)和环己烯为原料,通过硅氢加成催化合成了环己基甲基二氯硅烷(CMCS),采用红外光谱和色质联机等分析测试手段对产品进行了结构表征并逐一归属。
Addition reaction of methyldichlorosilane with natural producetion β-pinene;
甲基氢二氯硅烷与β-蒎烯硅氢化反应的研究
s:Several types of soluble polysilanes were prepared by the homopolymerization of methyldichlorosilane and its copolymerization with dimethyldiclorosilane.
以甲基氢二氯硅烷、二甲基二氯硅烷为原料 ,利用均聚和共聚的方法 ,合成了几种不同组成的可溶性聚硅烷 ,研究了反应条件对可溶性聚硅烷产率的影响 ,并用IR、XRD对产物进行了表征。
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